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41.
Joseph O'Donnell Pierre-André Cazade Sarah Guerin Ahmed Djeghader Ehtsham Ul Haq Kai Tao Ehud Gazit Eiichi Fukada Christophe Silien Tewfik Soulimane Damien Thompson Syed A. M. Tofail 《Advanced functional materials》2021,31(28):2100884
Controlling the electromechanical response of piezoelectric biological structures including tissues, peptides, and amino acids provides new applications for biocompatible, sustainable materials in electronics and medicine. Here, the piezoelectric effect is revealed in another class of biological materials, with robust longitudinal and shear piezoelectricity measured in single crystals of the transmembrane protein ba3 cytochrome c oxidase from Thermus thermophilus. The experimental findings from piezoresponse force microscopy are substantiated using a range of control measurements and molecular models. The observed longitudinal and shear piezoelectric responses of ≈ 2 and 8 pm V−1, respectively, are comparable to or exceed the performance of commonly used inorganic piezoelectric materials including quartz, aluminum nitride, and zinc oxide. This suggests that transmembrane proteins may provide, in addition to physiological energy transduction, technologically useful piezoelectric material derived entirely from nature. Membrane proteins could extend the range of rationally designed biopiezoelectric materials far beyond the minimalistic peptide motifs currently used in miniaturized energy harvesters, and the finding of robust piezoelectric response in a transmembrane protein also raises fundamental questions regarding the molecular evolution, activation, and role of regulatory proteins in the cellular nanomachinery, indicating that piezoelectricity might be important for fundamental physiological processes. 相似文献
42.
Ravi Radhakrishnan 《American Institute of Chemical Engineers》2021,67(3):e17026
Research problems in the domains of physical, engineering, biological sciences often span multiple time and length scales, owing to the complexity of information transfer underlying mechanisms. Multiscale modeling (MSM) and high-performance computing (HPC) have emerged as indispensable tools for tackling such complex problems. We review the foundations, historical developments, and current paradigms in MSM. A paradigm shift in MSM implementations is being fueled by the rapid advances and emerging paradigms in HPC at the dawn of exascale computing. Moreover, amidst the explosion of data science, engineering, and medicine, machine learning (ML) integrated with MSM is poised to enhance the capabilities of standard MSM approaches significantly, particularly in the face of increasing problem complexity. The potential to blend MSM, HPC, and ML presents opportunities for unbound innovation and promises to represent the future of MSM and explainable ML that will likely define the fields in the 21st century. 相似文献
43.
Mei Ying Liu Tu Lai Sun Xiao Li Zhu Xiao Qiang Liu He Tian Xiang Ming Chen 《Journal of the American Ceramic Society》2021,104(12):6393-6403
Hexagonal rare-earth ferrites (h-RFeO3) have attracted much scientific attention due to their room-temperature multiferroicity. However, it is still a hard job to obtain h-RFeO3 bulk materials because of the meta-stability of such hexagonal phase, and the evaluation of room-temperature ferroelectric and magnetoelectric characteristics in such materials is also a challengeable issue. In the present work, Yb1−xInxFeO3 ceramics with the stable hexagonal structure were obtained by introducing chemical pressure, where the unique ferroelectric domain structures of sixfold vortex combined with tenfold vortex with a typical size of ~400 nm were determined. Symmetry of the present system evolved from centrosymmetric orthorhombic Pbnm (x = 0–0.4) to non-centrosymmetric hexagonal P63cm (x = 0.5 and 0.6) with a ferroelectric polarization up to 3.2 μC/cm2, and finally to centrosymmetric hexagonal P63/mmc (x = 0.7 and 0.8). The Curie point decreased monotonically from 723 K to a temperature below room temperature with increasing x, and the antiferromagnetic phase transition above room temperature was determined for all compositions. Meanwhile, a large linear magnetoelectric coefficient (αME) up to 0.96 mV/cm Oe was obtained at room temperature, and this indicated the great application potential for magnetoelectric devices. 相似文献
44.
Sirish L. Shah Bhavik R. Bakshi Jinfeng Liu Christos Georgakis Benoit Chachuat Richard D. Braatz Brent R. Young 《American Institute of Chemical Engineers》2021,67(2):e17113
This white paper is the result of discussions during the FIPSE-4 conference ( http://fi-in-pse.org ) in June 2018. It aims to highlight open problems and provide directions for future research in the area of water with emphasis on its agricultural usages. Some of the open problems discussed are: (a) the use of ecosystems as unit operations to understand their role in providing freshwater and in cleaning polluted water; (b) consideration of interactions and independencies between flows of water and other resources, such as food, energy, materials, ecosystem services, and environmental emissions; (c) challenges in modeling, sensing, and closed-loop control in precision irrigation. In particular, the development of agro-hydrological models that balance computing speed versus solution details and accuracy: (d) The use of state and parameter estimation approaches, through field measurements, to obtain soil moisture levels accurately; and (e) decision support systems to administer water and nutrient needs for optimum yields of agricultural products. 相似文献
45.
Chemical engineering systems often involve a functional porous medium, such as in catalyzed reactive flows, fluid purifiers, and chromatographic separations. Ideally, the flow rates throughout the porous medium are uniform, and all portions of the medium contribute efficiently to its function. The permeability is a property of a porous medium that depends on pore geometry and relates flow rate to pressure drop. Additive manufacturing techniques raise the possibilities that permeability can be arbitrarily specified in three dimensions, and that a broader range of permeabilities can be achieved than by traditional manufacturing methods. Using numerical optimization methods, we show that designs with spatially varying permeability can achieve greater flow uniformity than designs with uniform permeability. We consider geometries involving hemispherical regions that distribute flow, as in many glass chromatography columns. By several measures, significant improvements in flow uniformity can be obtained by modifying permeability only near the inlet and outlet. 相似文献
46.
Gizem Ozbuyukkaya Robert S. Parker Goetz Veser 《American Institute of Chemical Engineers》2022,68(3):e17538
Accurate chemical kinetics are essential for reactor design and operation. However, despite recent advances in “big data” approaches, availability of kinetic data is often limited in industrial practice. Herein, we present a comparative proof-of-concept study for kinetic parameter estimation from limited data. Cross-validation (CV) is implemented to nonlinear least-squares (LS) fitting and evaluated against Markov chain Monte Carlo (MCMC) and genetic algorithm (GA) routines using synthetic data generated from a simple model reaction. As expected, conventional LS is fastest but least accurate in predicting true kinetics. MCMC and GA are effective for larger data sets but tend to overfit to noise for limited data. LS-CV strongly outperforms these methods at much reduced computational cost, especially for significant noise. Our findings suggest that implementation of CV with conventional regression provides an efficient approach to kinetic parameter estimation with high accuracy, robustness against noise, and only minimal increase in complexity. 相似文献
47.
《International Journal of Hydrogen Energy》2021,46(79):39011-39022
The main object of this research is the development of a mathematical framework to simulate a commercial ammonia plant and obtaining the optimal operating conditions of process at steady state condition. The considered ammonia plant consists of steam and autothermal reforming reactors, low and high temperature shift converters, hydrogen purification section, methanation, and ammonia synthesis reactors. The catalytic reactors are heterogeneously modeled based on the mass and energy balance equations considering heat and mass transfer resistances in the gas and catalyst phases. In addition, an equilibrium model is applied to simulate the absorption column. Then, the accuracy of developed framework is investigated against plant data. The results show that the internal mass transfer resistance in the commercial catalyst limits the syngas production in the reforming section. In the second step, an optimization problem is formulated to enhance the ammonia production considering safety and operating limitations. The formulated optimization problem is handled employing the genetic algorithm. The results show that more syngas production in the optimized hydrogen unit is one of the main reasons for higher ammonia synthesis in the considered plant. Applying optimal conditions on the process increases ammonia production potential from 1890 to 2179 mol s−1. 相似文献
48.
Mehmet B. Cil Ryan C. Hurley Lori Graham-Brady 《Journal of the American Ceramic Society》2019,102(9):5524-5534
Modeling the rate-dependent mechanical behavior of brittle granular materials is of interest to defense applications, civil and mining engineering, geology, and geophysics. In particular, granulated ceramics in armor systems play a significant role in the overall dynamic material response of ceramics, particularly in their penetration resistance. This paper presents a rate-dependent constitutive model for brittle granular materials based on a recent reformulation of breakage mechanics theory. The rate-dependency is introduced via the overstress theory of viscoplasticity. The proposed formulation incorporates the effects of relative density and particle grading on strength and porous compaction/dilation, and is capable of tracking their evolution. The model is devised with internal variables linked to underlying dissipative micromechanisms including configurational reorganization, particle breakage and frictional dissipation. A strategy for calibrating model parameters and required experiments are described. The impact of loading rate on shear strength and grading evolution are explored through a sensitivity analysis. The presented model is capable of capturing several key features of the experimentally observed behavior of brittle granular materials including stress-, rate- and density-dependent stress-strain and volume change responses, the competition between dilation and breakage-induced compaction, the evolving particle grading due to particle breakage, and the evolution toward a critical (steady) state under shearing. A possible application of this micromechanics-inspired modeling framework involves integrating it into rate-dependent models for ceramics to assist in improving the impact performance of next-generation ceramics. 相似文献
49.
Professor Utkin proposed an example showing that the amplitude of chattering caused by the presence of parasitic dynamics (stable actuators) in some systems governed by the First‐Order Sliding‐Mode Controller is lower than that produced by the Super‐Twisting Algorithm. This example served to motivate this paper reconsidering the problem of comparison of chattering in systems with stable actuators, and driven by Discontinuous Sliding‐Mode Controllers (DSMCs) and Continuous Sliding‐Mode Controllers (CSMCs). Comparison of chattering produced by DSMC and CSMC taking into account their amplitudes, frequencies, and average power (AP) needed to maintain the system into real‐sliding modes, allowing to conclude the following: (i) for systems with slow actuators, the amplitude of oscillations and AP produced by DSMC be smaller than those caused by CSMC; (ii) for bounded disturbances with fixed Lipschitz constant, there exist sufficiently fast actuators for which the amplitude of oscillations and AP produced by CSMC be smaller than those caused by DSMC. 相似文献
50.
文章研发了一款适用于机器人教育教学的多功能、多用途、普适性的19自由度的小型仿人机器人,主要完成了该机器人的机械结构设计与控制系统构建工作[1]。所设计的机器人机械结构可靠性高、工艺性好、结构紧凑、样式新颖;所构建的机器人控制系统鲁棒性高、稳定性好、控制准确、反应迅速,圆满地实现了预期的设计任务。通过对优缺点的综合对比,得出组合式构型方案在功能性、实用性和稳定性等方面具有明显优势,有望通过后续软件系统的开发提高其运动效能,真正在青少年机器人教育中发挥重要作用[2]。 相似文献